Hexa-substituted polyoxometalates made of trivacant Dawson {P2W15} fragments and {Ni6} clusters under hydrothermal conditions.

Authors :: Liu, Yong-Chao
Fu, Chun-Hua
Zheng, Shou-Tian
Zhao, Jun-Wei
Yang, Guo-Yu
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 2013, Vol. 42 Issue 48, p16676-16679, 4p
Publication Year :: 2013
Abstract: Three novel polyoxometalates (POMs) containing [Ni<subscript>6</subscript>(μ<subscript>3</subscript>-OH)<subscript>3</subscript>]<superscript>9−</superscript> and [P<subscript>2</subscript>W<subscript>15</subscript>O<subscript>56</subscript>]<superscript>12−</superscript> units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters. [ABSTRACT FROM AUTHOR]

Subjects :: POLYOXOMETALATES
TRANSITION metals
METAL ions
CHEMICAL reactions
MONOMERS
MAGNETIC susceptibility

Language :: English
ISSN :: 14779226
Volume :: 42
Issue :: 48
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 100893431
Full Text :: https://doi.org/10.1039/c3dt51786a

Full Text Access

Tools