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Hexa-substituted polyoxometalates made of trivacant Dawson {P2W15} fragments and {Ni6} clusters under hydrothermal conditions.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 2013, Vol. 42 Issue 48, p16676-16679, 4p
- Publication Year :
- 2013
-
Abstract
- Three novel polyoxometalates (POMs) containing [Ni<subscript>6</subscript>(μ<subscript>3</subscript>-OH)<subscript>3</subscript>]<superscript>9−</superscript> and [P<subscript>2</subscript>W<subscript>15</subscript>O<subscript>56</subscript>]<superscript>12−</superscript> units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 42
- Issue :
- 48
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 100893431
- Full Text :
- https://doi.org/10.1039/c3dt51786a