A 3d–4f heterometallic 3D POMOF based on lacunary Dawson polyoxometalates.

Authors :: Yu, Tingting
Ma, Huiyuan
Zhang, Chunjing
Pang, Haijun
Li, Shaobin
Liu, Heng
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 2013, Vol. 42 Issue 46, p16328-16333, 6p
Publication Year :: 2013
Abstract: A novel compound, Na<subscript>2</subscript>[Ce<subscript>4</subscript>(H<subscript>2</subscript>O)<subscript>22</subscript>(dpdo)<subscript>5</subscript>](Mn<subscript>2</subscript>HP<subscript>2</subscript>W<subscript>15</subscript>O<subscript>56</subscript>)<subscript>2</subscript>·8H<subscript>2</subscript>O (1) (dpdo = 4,4′-bipyridine-N,N′-dioxide) with 3d–4f heterometallic 3D POMOF that can be described as a self-penetrating (4,4,6)-connected net topology, has been isolated via a stepwise method, and its magnetic and electrocatalytic properties have been investigated. [ABSTRACT FROM AUTHOR]

Subjects :: POLYOXOMETALATES
MAGNETIC properties
ELECTROCATALYSIS
HETEROSTRUCTURES
BIPYRIDINE
CHEMICAL synthesis

Language :: English
ISSN :: 14779226
Volume :: 42
Issue :: 46
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 100893374
Full Text :: https://doi.org/10.1039/c3dt51983j