A fine tuning of metallaborane to bridged-boryl complex, [(CpRu)2(μ-H)(μ-CO)(μ-Bcat)] (cat = 1,2-O2C6H4; Cp = η5-C5Me5).

Authors :: Anju, R. S.
Roy, Dipak Kumar
Geetharani, K.
Mondal, Bijan
Varghese, Babu
Ghosh, Sundargopal
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 2013, Vol. 42 Issue 36, p12828-12831, 4p
Publication Year :: 2013
Abstract: Room temperature photolysis of [(Cp*RuCO)<subscript>2</subscript>BH<subscript>4</subscript>(Bcat)], 3, generated from the reaction of arachno-[(Cp*RuCO)<subscript>2</subscript>B<subscript>2</subscript>H<subscript>6</subscript>], 1, with HBcat (cat = 1,2-O<subscript>2</subscript>C<subscript>6</subscript>H<subscript>4</subscript>), yielded a rare homodinuclear bridged-boryl complex, [(Cp*Ru)<subscript>2</subscript>(μ-H)(μ-CO)(μ-Bcat)], 4, confirmed by X-ray diffraction. [ABSTRACT FROM AUTHOR]

Subjects :: PHOTOLYSIS (Chemistry)
BORON compounds
METAL complexes
X-ray diffraction
REACTIVITY (Chemistry)

Language :: English
ISSN :: 14779226
Volume :: 42
Issue :: 36
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 100892973
Full Text :: https://doi.org/10.1039/c3dt51138c

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