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A bimodal anionic MOF: turn-off sensing of CuII and specific sensitization of EuIII.
- Source :
- Chemical Communications; 2014, Vol. 50 Issue 88, p13567-13570, 4p
- Publication Year :
- 2014
-
Abstract
- A novel porous anionic MOF {[Mg<subscript>3</subscript>(ndc)<subscript>2.5</subscript>(HCO<subscript>2</subscript>)<subscript>2</subscript>(H<subscript>2</subscript>O)][NH<subscript>2</subscript>Me<subscript>2</subscript>]⋅2H<subscript>2</subscript>O⋅DMF} (1) having exchangeable dim ethyl amine cations in 1D channels has been synthesized and characterized. Through cation exchange, 1 manifests bimodal functionality, being a turn-off sensor of Cu<superscript>II</superscript> on one hand, and a selective sensitizer of Eu<superscript>III</superscript> emitting intense pure red emission on the other. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 50
- Issue :
- 88
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100188961
- Full Text :
- https://doi.org/10.1039/c4cc05991c