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Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes.
- Source :
- Chemical Communications; 2014, Vol. 50 Issue 69, p9876-9878, 3p
- Publication Year :
- 2014
-
Abstract
- Regioselective cycloaddition of adamantylidene carbene to Pr@C<subscript>2v</subscript>(9)-C<subscript>82</subscript> affords the first derivative of praseodymium-containing metallo-fullerenes. Single-crystal X-ray crystallographic data in combination with theoretical studies demonstrate that the addition is dictated by the single metal ion encapsulated inside the fullerene cage. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 50
- Issue :
- 69
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100136719
- Full Text :
- https://doi.org/10.1039/c4cc02949f