Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In4(μ2-OH)3} building block based metal organic framework through a dinuclear complex.

Authors :: Xin-Ming Wang
Rui-Qing Fan
Liang-Sheng Qiang
Ping Wang
Yu-Lin Yang
Yu-Lei Wang
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 2014, Vol. 43 Issue 43, p16152-16155, 4p
Publication Year :: 2014
Abstract: A rare 3D tetranuclear {In<subscript>4</subscript>(μ<subscript>2</subscript>-OH)<subscript>3</subscript>} building block based MOF {[In<subscript>4</subscript>/3(μ<subscript>2</subscript>-OH)(2,6-pydc)(1,4-bda)<subscript>0.5</subscript>(H<subscript>2</subscript>O)]·2H<subscript>2</subscript>O}<subscript>n</subscript> (2) was obtained through a crystal transformation from a dimeric complex In<subscript>3</subscript>(2,6-pydc)<subscript>3</subscript>(1,4-bda)<subscript>1.5</subscript>(H<subscript>2</subscript>O)<subscript>6</subscript> (1). With a 2D + 3D 3D compact structure, 2 retains crystallinity in boiling water and organic solvents, exhibiting exceptional fluorescence quenching behaviour for the DMSO molecule. [ABSTRACT FROM AUTHOR]

Subjects :: BOILING water reactors
CRYSTALLINITY
ORGANIC solvents
DIMERIC ions
FLUORESCENCE

Language :: English
ISSN :: 14779226
Volume :: 43
Issue :: 43
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 100113052
Full Text :: https://doi.org/10.1039/c4dt02045f

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