Emissive molecular nanomagnets: introducing optical properties in triangular oximato {MnIII3} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues.

Authors :: Alexandropoulos, Dimitris I.
Mowson, Andrew M.
Pilkington, Melanie
Bekiari, Vlasoula
Christou, George
Stamatatos, Theocharis C.
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 2014, Vol. 43 Issue 5, p1965-1969, 5p
Publication Year :: 2014
Abstract: The targeted replacement of acetate groups in the optically inactive [Mn<superscript>III</superscript><subscript>3</subscript>O(O<subscript>2</subscript>CMe)<subscript>3</subscript>(mpko)<subscript>3</subscript>](ClO<subscript>4</subscript>) single-molecule magnet with their naphthalene, anthracene, and pyrene fluorescent analogues has led to three new emissive SMMs with enhanced photo-luminescence properties and potential applications in the field of molecular electronics. [ABSTRACT FROM AUTHOR]

Subjects :: NANOMAGNETICS
CARBOXYLATES
LIGANDS (Chemistry)
NAPHTHALENE
ANTHRACENE
PYRENE
PHOTOLUMINESCENCE
MOLECULAR electronics

Language :: English
ISSN :: 14779226
Volume :: 43
Issue :: 5
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 100105276
Full Text :: https://doi.org/10.1039/c3dt52571f

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