Precise study of asymptotic physics with subradiant ultracold molecules.

Weakly bound molecules have physical properties without atomic analogues, even as the bond length approaches dissociation. For instance, the internal symmetries of homonuclear diatomic molecules result in the formation of two-body superradiant and subradiant excited states. Whereas superradiance has been demonstrated in a variety of systems, subradiance is more elusive owing to the inherently weak interaction with the environment. Here we characterize the properties of deeply subradiant molecular states with intrinsic quality factors exceeding 10¹³ via precise optical spectroscopy with the longest molecule-light coherent interaction times to date. We find that two competing effects limit the lifetimes of the subradiant molecules, with different asymptotic behaviours. The first is radiative decay via weak magnetic-dipole and electric-quadrupole interactions. We prove that its rate increases quadratically with the bond length, confirming quantum mechanical predictions. The second is non-radiative decay through weak gyroscopic predissociation, with a rate proportional to the vibrational mode spacing and sensitive to short-range physics. This work bridges the gap between atomic and molecular metrology based on lattice-clock techniques, enhancing our understanding of long-range interatomic interactions. [ABSTRACT FROM AUTHOR]