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Tuning pore size in a zirconium--tricarboxylate metal--organic framework.
- Source :
- CrystEngComm; 2014, Vol. 16 Issue 29, p6530-6533, 4p
- Publication Year :
- 2014
-
Abstract
- The water-stable zirconium--tricarboxylate series of frameworks, [Zr<subscript>6</subscript>O<subscript>4</subscript>(OH)<subscript>4</subscript>(X)<subscript>6</subscript>(btc)<subscript>2</subscript>]⋅nH<subscript>2</subscript>O, where X = formate (F), acetate (A), or propionate (P), exhibit tunable porosity by virtue of systematic modulation of the chain length of the monocarboxylate ligand X. This modification not only impacts the pore size of the framework, but provides an important avenue for the construction of mixed-linker MOFs. [ABSTRACT FROM AUTHOR]
- Subjects :
- ZIRCONIUM
FORMATES
LIGANDS (Chemistry)
ACETATES
PROPIONATES
Subjects
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 16
- Issue :
- 29
- Database :
- Complementary Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 100092978
- Full Text :
- https://doi.org/10.1039/c4ce01031k