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Synthesis of Trifluoromethylated Cycloheptatrienes from N-Tosylhydrazones: Transition-Metal-Free Büchner Ring Expansion.

Authors :
Zhikun Zhang
Jiajie Feng
Yan Xu
Songnan Zhang
Yuxuan Ye
Tianjiao Li
Xi Wang
Jun Chen
Yan Zhang
Jianbo Wang
Source :
Synlett; 2015, Vol. 26 Issue 1, p59-62, 4p
Publication Year :
2015

Abstract

A transition-metal-free Büchner reaction using trifluoromethylated N-tosylhydrazones as substrates is reported. A series of trifluoromethylated cycloheptatriene derivatives can be synthesized by this straight forward method. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09365214
Volume :
26
Issue :
1
Database :
Complementary Index
Journal :
Synlett
Publication Type :
Academic Journal
Accession number :
100013591
Full Text :
https://doi.org/10.1055/s-0034-1378937