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Catalytic Water Oxidation by Ruthenium(II) Quaterpyridine (qpy) Complexes: Evidence for Ruthenium(III) qpy- N, N′′′-dioxide as the Real Catalysts.
- Source :
- Angewandte Chemie International Edition; Dec2014, Vol. 53 Issue 52, p14468-14471, 4p
- Publication Year :
- 2014
-
Abstract
- Polypyridyl and related ligands have been widely used for the development of water oxidation catalysts. Supposedly these ligands are oxidation-resistant and can stabilize high-oxidation-state intermediates. In this work a series of ruthenium(II) complexes [Ru(qpy)(L)<subscript>2</subscript>]<superscript>2+</superscript> (qpy=2,2′:6′,2′′:6′′,2′′′-quaterpyridine; L=substituted pyridine) have been synthesized and found to catalyze Ce<superscript>IV</superscript>-driven water oxidation, with turnover numbers of up to 2100. However, these ruthenium complexes are found to function only as precatalysts; first, they have to be oxidized to the qpy- N, N′′′-dioxide (ONNO) complexes [Ru(ONNO)(L)<subscript>2</subscript>]<superscript>3+</superscript> which are the real catalysts for water oxidation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 53
- Issue :
- 52
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 100011166
- Full Text :
- https://doi.org/10.1002/anie.201408795