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Facile green treatment of mixed cellulose ester membranes by deep eutectic solvent to enhance dye removal and determination.
Facile green treatment of mixed cellulose ester membranes by deep eutectic solvent to enhance dye removal and determination.
- Source :
-
International journal of biological macromolecules [Int J Biol Macromol] 2025 Feb; Vol. 291, pp. 139100. Date of Electronic Publication: 2024 Dec 24. - Publication Year :
- 2025
-
Abstract
- Synthetic dye production and the consequent generation of dye-rich wastewater are major concerns of water quality in many countries. We developed a sustainable approach with deep eutectic solvent (DES) treatment to enhance the efficiency of mixed cellulose ester (MCE) membrane-based dye removal material. The DES composition and treatment conditions were optimized, and the treated membranes were comprehensively characterized. DES-treated membranes exhibited improved morphology, surface properties, and superior dye adsorption capabilities. Our study revealed that the adsorption process was chemically controlled and driven by electrostatic and hydrogen bond interactions. Thermodynamic analysis confirmed the endothermic and spontaneous nature of the adsorption process. Moreover, the treated membranes exhibited good separation performance for dye/salt mixtures. Additionally, we demonstrated selective adsorption of cationic dyes over anionic dyes using these treated membranes. This selectivity enabled the development of a membrane solid-phase extraction (MSPE) method for quantification of trace amount of dyes. Compared with other methods, DES-treated MCE membranes present a promising solution for efficient dye quantification and removal, offering a green and effective strategy to address water pollution stemming from synthetic dyes. Additionally, this study provides a novel strategy for green chemistry modification of cellulose-based materials.<br />Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.<br /> (Copyright © 2024 Elsevier B.V. All rights reserved.)
- Subjects :
- Adsorption
Water Purification methods
Esters chemistry
Solid Phase Extraction methods
Thermodynamics
Cellulose chemistry
Coloring Agents chemistry
Coloring Agents isolation & purification
Solvents chemistry
Membranes, Artificial
Water Pollutants, Chemical chemistry
Water Pollutants, Chemical isolation & purification
Green Chemistry Technology methods
Subjects
Details
- Language :
- English
- ISSN :
- 1879-0003
- Volume :
- 291
- Database :
- MEDLINE
- Journal :
- International journal of biological macromolecules
- Publication Type :
- Academic Journal
- Accession number :
- 39725107
- Full Text :
- https://doi.org/10.1016/j.ijbiomac.2024.139100