High Relative Humidity-Induced Growth of Perovskite Nanowires from Glass toward Single-Mode Photonic Nanolasers at Sub-100-nm Scale.

Metal halide perovskites (MHPs) have achieved substantial progress in their applications; however, their ionic crystal character and low formation energy result in poor structural stability and limited morphological tunability. In particular, high relative humidity (RH) commonly causes severe MHP degradation, which poses a major obstacle to long-term device operation. Herein, high RH-induced growth of anisotropic MHP structures on glass surfaces is reported under 25 °C and atmospheric conditions on a basis of glass corrosion by moisture. Nanowires (NWs) with tunable length and composition are obtained under 85% RH air, and water molecule-induced facet engineering of perovskite is established for anisotropic growth. Importantly, single-mode photonic lasing in these MHP NWs with thickness at sub-100-nm scale (down to 75 nm ∼ 1/7 lasing wavelength) is achieved via both one-photon and multiphoton pumping. These nanowire lasers exhibited high quality factor (>3000), high degree of polarization (≈0.9), and excellent stability under laser irradiation. The work not only presents a distinctive technique for the growth of MHPs but also endows MHP NWs with new opportunities for nonlinear optics, strong light-matter interactions, and active photonic integrated devices.
(© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.)