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Degradation of Rhodamine B by Visible Light Driven MoO 3 @TiO 2 Core-Shell Photocatalyst.
- Source :
-
Langmuir : the ACS journal of surfaces and colloids [Langmuir] 2024 Nov 12; Vol. 40 (45), pp. 24029-24036. Date of Electronic Publication: 2024 Nov 04. - Publication Year :
- 2024
-
Abstract
- In this study, a MoO <subscript>3</subscript> @TiO <subscript>2</subscript> composite core-shell material was developed to remove Rhodamine B (RhB) dye through synergistic adsorption and photocatalytic degradation. n-n heterostructures were formed by coupling n-type semiconductors to enhance the efficiency of photocarrier separation and photocatalytic performance. MoO <subscript>3</subscript> , which possesses strong adsorption capacity, was primarily used as a dye adsorbent. Additionally, the formation of an n-n heterojunction with TiO <subscript>2</subscript> enabled MoO <subscript>3</subscript> to expand the photocorresponding range of TiO <subscript>2</subscript> , leading to the generation of superoxide (O <subscript>2</subscript> <superscript>•</superscript> ) and hydroxyl ( <superscript>•</superscript> OH) free radicals for dye degradation. The experimental results demonstrate that the MoO <subscript>3</subscript> @TiO <subscript>2</subscript> core-shell composite exhibits excellent performance for RhB dye removal, with adsorption and degradation rates reaching 35.7 and 70.3%, respectively, even at low catalyst concentrations. This approach offers new insights into the development of MoO <subscript>3</subscript> core-shell photocatalysts.
Details
- Language :
- English
- ISSN :
- 1520-5827
- Volume :
- 40
- Issue :
- 45
- Database :
- MEDLINE
- Journal :
- Langmuir : the ACS journal of surfaces and colloids
- Publication Type :
- Academic Journal
- Accession number :
- 39494805
- Full Text :
- https://doi.org/10.1021/acs.langmuir.4c03333