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Degradation of Rhodamine B by Visible Light Driven MoO 3 @TiO 2 Core-Shell Photocatalyst.

Authors :
Liu H
Qiao P
Liu Y
Guo X
Liu Y
Song H
Wang X
Wang W
Source :
Langmuir : the ACS journal of surfaces and colloids [Langmuir] 2024 Nov 12; Vol. 40 (45), pp. 24029-24036. Date of Electronic Publication: 2024 Nov 04.
Publication Year :
2024

Abstract

In this study, a MoO <subscript>3</subscript> @TiO <subscript>2</subscript> composite core-shell material was developed to remove Rhodamine B (RhB) dye through synergistic adsorption and photocatalytic degradation. n-n heterostructures were formed by coupling n-type semiconductors to enhance the efficiency of photocarrier separation and photocatalytic performance. MoO <subscript>3</subscript> , which possesses strong adsorption capacity, was primarily used as a dye adsorbent. Additionally, the formation of an n-n heterojunction with TiO <subscript>2</subscript> enabled MoO <subscript>3</subscript> to expand the photocorresponding range of TiO <subscript>2</subscript> , leading to the generation of superoxide (O <subscript>2</subscript> <superscript>•</superscript> ) and hydroxyl ( <superscript>•</superscript> OH) free radicals for dye degradation. The experimental results demonstrate that the MoO <subscript>3</subscript> @TiO <subscript>2</subscript> core-shell composite exhibits excellent performance for RhB dye removal, with adsorption and degradation rates reaching 35.7 and 70.3%, respectively, even at low catalyst concentrations. This approach offers new insights into the development of MoO <subscript>3</subscript> core-shell photocatalysts.

Details

Language :
English
ISSN :
1520-5827
Volume :
40
Issue :
45
Database :
MEDLINE
Journal :
Langmuir : the ACS journal of surfaces and colloids
Publication Type :
Academic Journal
Accession number :
39494805
Full Text :
https://doi.org/10.1021/acs.langmuir.4c03333