Ambient Moisture-Induced Self Alignment of Polarization in Ferroelectric Hafnia.

The discovery of nanoscale ferroelectricity in hafnia (HfO ₂ ) has paved the way for next generation high-density, non-volatile devices. Although the surface conditions of nanoscale HfO ₂ present one of the fundamental mechanism origins, the impact of external environment on HfO ₂ ferroelectricity remains unknown. In this study, the deleterious effect of ambient moisture is examined on the stability of ferroelectricity using Hf _0.5 Zr _0.5 O ₂ (HZO) films as a model system. It is found that the development of an intrinsic electric field due to the adsorption of atmospheric water molecules onto the film's surface significantly impairs the properties of domain retention and polarization stability. Nonetheless, vacuum heating efficiently counteracts the adverse effects of water adsorption, which restores the symmetric electrical characteristics and polarization stability. This work furnishes a novel perspective on previous extensive studies, demonstrating significant impact of surface water on HfO ₂ -based ferroelectrics, and establishes the design paradigm for the future evolution of HfO ₂ -based multifunctional electronic devices.
(© 2024 The Author(s). Advanced Science published by Wiley‐VCH GmbH.)