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An l-isosorbide-based reactive chiral dopant with high helical twisting power for cholesteric liquid crystal polymers reflecting left-handed circularly polarized light.
- Source :
-
Organic chemistry frontiers : an international journal of organic chemistry [Org Chem Front] 2024 Oct 09; Vol. 11 (24), pp. 7053-7058. Date of Electronic Publication: 2024 Oct 09 (Print Publication: 2024). - Publication Year :
- 2024
-
Abstract
- For visible light reflective cholesteric liquid crystal polymers, reactive chiral dopant enantiomers with high helical twisting power are attractive. However, a chiral dopant for reflecting left-handed circularly polarized light has been missing so far. Here, we report the synthesis of a reactive, left-handed, l-isosorbide-based chiral dopant with a high helical twisting power of -48 μm <superscript>-1</superscript> that can be used in visible light reflective cholesteric liquid crystal polymers. The right handed dopant enantiomer was also synthesized, showing a helical twisting power of +63 μm <superscript>-1</superscript> .<br />Competing Interests: There are no conflicts to declare.<br /> (This journal is © the Partner Organisations.)
Details
- Language :
- English
- ISSN :
- 2052-4110
- Volume :
- 11
- Issue :
- 24
- Database :
- MEDLINE
- Journal :
- Organic chemistry frontiers : an international journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 39444415
- Full Text :
- https://doi.org/10.1039/d4qo01672f