Back to Search Start Over

An l-isosorbide-based reactive chiral dopant with high helical twisting power for cholesteric liquid crystal polymers reflecting left-handed circularly polarized light.

Authors :
Dinc RU
Lub J
Kragt AJJ
Schenning APHJ
Source :
Organic chemistry frontiers : an international journal of organic chemistry [Org Chem Front] 2024 Oct 09; Vol. 11 (24), pp. 7053-7058. Date of Electronic Publication: 2024 Oct 09 (Print Publication: 2024).
Publication Year :
2024

Abstract

For visible light reflective cholesteric liquid crystal polymers, reactive chiral dopant enantiomers with high helical twisting power are attractive. However, a chiral dopant for reflecting left-handed circularly polarized light has been missing so far. Here, we report the synthesis of a reactive, left-handed, l-isosorbide-based chiral dopant with a high helical twisting power of -48 μm <superscript>-1</superscript> that can be used in visible light reflective cholesteric liquid crystal polymers. The right handed dopant enantiomer was also synthesized, showing a helical twisting power of +63 μm <superscript>-1</superscript> .<br />Competing Interests: There are no conflicts to declare.<br /> (This journal is © the Partner Organisations.)

Details

Language :
English
ISSN :
2052-4110
Volume :
11
Issue :
24
Database :
MEDLINE
Journal :
Organic chemistry frontiers : an international journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
39444415
Full Text :
https://doi.org/10.1039/d4qo01672f