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2D Microporous Polymers/Reduced Graphene Oxide with Built-In Lithiophilic Sites for Uniform Lithium Deposition in Lithium Metal Anode.
- Source :
-
Small (Weinheim an der Bergstrasse, Germany) [Small] 2024 Oct 13, pp. e2406248. Date of Electronic Publication: 2024 Oct 13. - Publication Year :
- 2024
- Publisher :
- Ahead of Print
-
Abstract
- Lithium (Li) metal is an attractive anode material for use in high-energy lithium-sulfur and lithium-air batteries. However, its practical application is severely impeded by excessive dendrite growth, huge volume changes, and severe side reactions. Herein, a novel Li metal anode composed of lithiophilic two dimensional (2D) conjugated microporous polymer (Li-CMP) and reduced graphene oxide (rGO) sandwiches (Li-CMP@rGO) for Li metal batteries (LiMBs) is reported. In the Li-CMP@rGO anode, the conductive rGO facilitates the charge transfer while the functionalized-CMP provides Li nucleation sites within the micropores, thereby preventing dendrite growth. As a result, the Li-CMP@rGO anode can be cycled smoothly at 6 mA cm <superscript>-2</superscript> of current density with a platting capacity of 2 mAh cm <superscript>-2</superscript> for 1000 h. A Coulombic efficiency of 98.4% is achieved over 350 cycles with a low overpotential of 28 mV. In a full cell with LiFePO <subscript>4</subscript> cathode, the Li-CMP@rGO anode also exhibited good cycling stability compared to CMP@rGO and CMP/Super-P. As expected, the simulation results reveal that Li-CMP@rGO has a strong affinity for Li ions compared to CMP@rGO. The strategies adopted in this work can open new avenues for designing hybrid porous host materials for developing safe and stable Li metal anodes.<br /> (© 2024 Wiley‐VCH GmbH.)
Details
- Language :
- English
- ISSN :
- 1613-6829
- Database :
- MEDLINE
- Journal :
- Small (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 39396373
- Full Text :
- https://doi.org/10.1002/smll.202406248