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Facile interconversion of mesitylcopper into a CuMes-Cu 2 bis(amidinate) triangle and a tetracuprous Möbius strip.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Oct 01; Vol. 60 (79), pp. 11136-11139. Date of Electronic Publication: 2024 Oct 01. - Publication Year :
- 2024
-
Abstract
- A new flexible bis(amidine) ligand featuring two additional N-donor groups incorporates a defined [Cu <superscript>I</superscript> MesCu <subscript>2</subscript> <superscript>I</superscript> ] <superscript>2+</superscript> fragment from mesitylcopper into a triangular cluster with a reactive organometallic coordination site. Subtle changes to the reaction protocol result in the formation of an intertwined tetracuprous arrangement that adopts the shape of a Möbius strip.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 60
- Issue :
- 79
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 39279559
- Full Text :
- https://doi.org/10.1039/d4cc03935a