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Sustainable management of medical plastic waste through carbon dioxide-assisted pyrolysis.

Authors :
Kim JY
Park J
Lee DJ
Choi YB
Kwon EE
Source :
Chemosphere [Chemosphere] 2024 Sep; Vol. 364, pp. 143266. Date of Electronic Publication: 2024 Sep 04.
Publication Year :
2024

Abstract

To address the challenges associated with medical plastic waste and to characterize its heterogeneity, non-recyclability, and potential biohazard risks, this study explored a carbon dioxide (CO <subscript>2</subscript> )-assisted pyrolysis process as a sustainable disposal method. Medical plastic waste typically includes polypropylene, polystyrene, and polyvinyl chloride. To experimentally evaluate the functional reactivity of CO <subscript>2</subscript> , we employed three pyrolysis setups (one-stage, two-stage, and catalytic processes). The technical advantages of using CO <subscript>2</subscript> over inert gases such as nitrogen (N <subscript>2</subscript> ) were demonstrated through pyrolysis tests. The results showed that energy production was enhanced under CO <subscript>2</subscript> conditions, with catalytic pyrolysis generating 146% more flammable gases compared to pyrolysis in an N <subscript>2</subscript> environment. The use of CO <subscript>2</subscript> also led to a reduction in the formation of toxic chemicals due to improved thermal cracking. The CO <subscript>2</subscript> -assisted pyrolysis process exhibited net negative CO <subscript>2</subscript> emissions when a catalyst was present, as a substantial amount of CO <subscript>2</subscript> was consumed during the process. In conclusion, CO <subscript>2</subscript> -assisted pyrolysis of medical plastic waste offers a sustainable management solution that maximizes the utilization of carbon resources.<br />Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.<br /> (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Details

Language :
English
ISSN :
1879-1298
Volume :
364
Database :
MEDLINE
Journal :
Chemosphere
Publication Type :
Academic Journal
Accession number :
39241841
Full Text :
https://doi.org/10.1016/j.chemosphere.2024.143266