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Chiral bifunctional sulfide-catalyzed enantioselective bromolactonizations of α- and β-substituted 5-hexenoic acids.
- Source :
-
Beilstein journal of organic chemistry [Beilstein J Org Chem] 2024 Jul 30; Vol. 20, pp. 1794-1799. Date of Electronic Publication: 2024 Jul 30 (Print Publication: 2024). - Publication Year :
- 2024
-
Abstract
- Enantioselective halolactonizations of sterically less hindered alkenoic acid substrates without substituents on the carbon-carbon double bond have remained a formidable challenge. To address this limitation, we report herein the asymmetric bromolactonization of 5-hexenoic acid derivatives catalyzed by a BINOL-derived chiral bifunctional sulfide.<br /> (Copyright © 2024, Sumida et al.)
Details
- Language :
- English
- ISSN :
- 1860-5397
- Volume :
- 20
- Database :
- MEDLINE
- Journal :
- Beilstein journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 39109297
- Full Text :
- https://doi.org/10.3762/bjoc.20.158