Luminescent Cs 8 PbBr 6 4+ Quantum Dots Centered on the Octahedral PbBr 6 4- Cluster within Zeolite LTA: Exploring the Edge of Three-Dimensional Crystal Structure and Its Stability.

The perovskite quantum dots (QDs) of CsPbX ₃ (X = Cl, Br, I) exhibit exceptional photoluminescent properties, but their sensitivity to moisture and heat poses a challenge. This study presents a solvent-free synthesis approach for incorporating CsPbBr ₃ perovskite QDs into zeolite A. The introduction of [Cs ₈ PbBr ₆ ] ⁴⁺ perovskite QDs into the zeolite framework resulted in a highly stable configuration, maintaining its initial luminescence properties even after being underwater or exposed to heat. The structure is determined by 3-dimensional single-crystal crystallography. Each octahedral PbBr ₆ ^4- ion is surrounded by Cs ⁺ ions and [Cs ₈ PbBr ₆ ] ⁴⁺ perovskite QDs being formed at the 32% of the center of a large cavity. Further, [Na ₁₂ CsBr ₈ ] ⁵⁺ QDs are formed at the very center of another 46% large cavities by combining Cs ⁺ , Na ⁺ , and Br ^- ions. The peak in the emission spectrum of Pb,Br,Cs,Na-A is similar to those of the CsPbBr ₃ nanocrystal, Cs ₄ PbBr ₆ 0-dimensional perovskite QDs, and Pb,Br,H,Cs,Na-FAU(X and Y). This work demonstrates that Pb,Br,Cs,Na-A can be produced using a simplified solvent-free synthesis procedure, which exhibits excellent stability against moisture and heat. Moreover, through a straightforward process, various quantum dots (QDs) can be incorporated into zeolite cavities to develop materials with variety photoluminescent properties.