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Changing Benzoxazole Ring into Nonring Imine Linkages on Covalent Organic Frameworks with Tuning H 2 O 2 Photosynthesis Performance.
- Source :
-
ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2024 Jul 31; Vol. 16 (30), pp. 40180-40189. Date of Electronic Publication: 2024 Jul 17. - Publication Year :
- 2024
-
Abstract
- Two π-conjugated covalent organic frameworks (COFs) with nonring imine or benzoxazole ring linkages were prepared by reacting 3,3'-dihydrooxybenzidine (BDOH) with 3,5-triformylbenzene (Tb) in the presence or absence of benzimidazole (BDOH-Tb- IM and BDOH-Tb- BO ). Although two COFs indicated similar composition, crystalline structures, and morphologies, imine-based BDOH-Tb- IM exhibited a photocatalytic H <subscript>2</subscript> O <subscript>2</subscript> production rate of 2490 μmol·g <superscript>-1</superscript> ·h <superscript>-1</superscript> in sacrificial reagent-free pure water, higher than that of benzoxazole-based BDOH-Tb- BO-a (1168 μmol·g <superscript>-1</superscript> ·h <superscript>-1</superscript> ). The higher photocatalytic activity of BDOH-Tb- IM was attributed to its more efficient photoinduced charge separation and utilization efficiency and different 2e <superscript>-</superscript> ORR active sites over the two COFs. This study demonstrated an available ring effect to adjust photocatalytic performance between π-conjugated COFs.
Details
- Language :
- English
- ISSN :
- 1944-8252
- Volume :
- 16
- Issue :
- 30
- Database :
- MEDLINE
- Journal :
- ACS applied materials & interfaces
- Publication Type :
- Academic Journal
- Accession number :
- 39016448
- Full Text :
- https://doi.org/10.1021/acsami.4c06179