Cobalt-Doped Ceria Sensitizer Effects on Metal Oxide Nanofibers: Heightened Surface Reactivity for High-Performing Chemiresistive Sensors.

Chemiresistive gas sensors based on semiconducting metal oxides typically rely on noble metal catalysts to enhance their sensitivity and selectivity. However, noble metal catalysts have several drawbacks for practical utilization, including their high cost, their propensity for spontaneous agglomeration, and poisoning effects with certain types of gases. As such, in the interest of commercializing the chemiresistive gas sensor technology, we propose an alternative design for a noble-metal-free sensing material through the case study of Co-doped ceria (Co-CeO ₂ ) catalysts embedded in a SnO ₂ matrix. In this investigation, we utilized electrospinning and subsequent calcination to prepare Co-CeO ₂ catalyst nanoparticles integrated with SnO ₂ nanofibers (NFs) with uniform particle distribution and particle size regulation down to the sub-2 nm regime. The resulting Co-CeO ₂ @SnO ₂ NFs exhibited superior gas sensing characteristics toward isoprene (C ₅ H ₈ ) gas, a significant biomarker for monitoring the onset of various diseases through breath diagnostics. In particular, we identified that the Co-CeO ₂ catalysts, owing to the transition metal doping, facilitated the spillover of chemisorbed oxygen species to the SnO ₂ sensing body. This resulting in the sensor having a 27.4-fold higher response toward 5 ppm of C ₅ H ₈ (compared to pristine SnO ₂ ), exceptionally high selectivity, and a low detection limit of 100 ppb. The sensor also exhibited high stability for prolonged response-recovery cycles, attesting to the strong anchoring of Co-CeO ₂ catalysts in the SnO ₂ matrix. Based on our findings, the transition metal-doped metal oxide catalysts, such as Co-CeO ₂ , demonstrate strong potential to completely replace noble metal catalysts, thereby advancing the development of the commercially viable chemiresistive gas sensors free from noble metals, capable of detecting target gases at sub-ppm levels.