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High Ductility and Excellent Thermoelectric Performance in Te-Stabilized Cubic Ag 2 Te x S 1- x Solid Solutions.
- Source :
-
ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2024 Jul 17; Vol. 16 (28), pp. 36637-36648. Date of Electronic Publication: 2024 Jul 05. - Publication Year :
- 2024
-
Abstract
- The stabilization at low temperatures of the Ag <subscript>2</subscript> S cubic phase could afford the design of high-performance thermoelectric materials with excellent mechanical behavior, enabling them to withstand prolonged vibrations and thermal stress. In this work, we show that the Ag <subscript>2</subscript> Te <subscript> x </subscript> S <subscript>1- x </subscript> solid solutions, with Te content within the optimal range 0.20 ≤ x ≤ 0.30, maintain a stable cubic phase across a wide temperature range from 300 to 773 K, thus avoiding the detrimental phase transition from monoclinic to cubic phase observed in Ag <subscript>2</subscript> S. Notably, the Ag <subscript>2</subscript> Te <subscript> x </subscript> S <subscript>1- x </subscript> (0.20 ≤ x ≤ 0.30) samples showed no fractures during bending tests and displayed superior ductility at room temperature compared to Ag <subscript>2</subscript> S, which fractured at a strain of 6.6%. Specifically, the Ag <subscript>2</subscript> Te <subscript>0.20</subscript> S <subscript>0.80</subscript> sample demonstrated a bending average yield strength of 46.52 MPa at 673 K, significantly higher than that of Ag <subscript>2</subscript> S, whose bending average yield strength dropped from 80.15 MPa at 300 K to 12.66 MPa at 673 K. Furthermore, the thermoelectric performance of the Ag <subscript>2</subscript> Te <subscript> x </subscript> S <subscript>1- x </subscript> (0.20 ≤ x ≤ 0.30) samples surpassed that of both InSe and pure Ag <subscript>2</subscript> S, with the Ag <subscript>2</subscript> Te <subscript>0.30</subscript> S <subscript>0.70</subscript> sample achieving the highest ZT value of 0.59 at 723 K. These results indicate substantial potential for practical applications due to enhanced durability and thermoelectric performance.
Details
- Language :
- English
- ISSN :
- 1944-8252
- Volume :
- 16
- Issue :
- 28
- Database :
- MEDLINE
- Journal :
- ACS applied materials & interfaces
- Publication Type :
- Academic Journal
- Accession number :
- 38968080
- Full Text :
- https://doi.org/10.1021/acsami.4c08819