Mie Resonant Metal Oxide Nanospheres for Broadband Photocatalytic Enhancements.

Metal oxides are widely used in heterogeneous catalysis as supports to disperse catalytically active nanoparticles, isolated atomic sites, or even as catalysts themselves. Herein, we present a method to produce optically active metal oxide supports that exhibit size-dependent Mie resonances based on TiO ₂ nanospheres with tunable size, crystalline phase composition, and optical properties. Mie resonant TiO ₂ nanospheres were used as supports to disperse Au, Pt, and Pd nanoparticles. We have found up to a 50-fold enhancement of the electric field at the metal oxide/metal interface corresponding to wavelength-dependent multipolar resonances in the TiO ₂ structure. Using Au/TiO ₂ as a prototypical photocatalyst, we demonstrate broadband rate enhancements between 400 and 800 nm during CO oxidation, with a noticeable increase below 500 nm. This increased reactivity at higher photon energies is due to improved photon utilization and interband absorption in the gold that results in greater secondary electron generation through electron-electron scattering processes, thus leading to higher rates in conjunction with the Mie scattering TiO ₂ support. This study not only highlights the potential of Mie resonant TiO ₂ in broadband photocatalytic enhancements but also for developing various Mie resonant metal oxide supports, such as ZnO or Cu ₂ O, which can improve photocatalytic performance for a number of critical reactions. As the chemical and energy industries move toward conversion technologies driven by renewable energy sources, the strategy of designing optical resonances into oxide supports that are already widely used could enable a straightforward adaptation of photochemical processing based on traditional heterogeneous catalysts.