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Alkyl nitrite-enabled palladium-catalyzed terminal selective oxidative cyclization of 4-penten-1-ols.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jul 16; Vol. 60 (58), pp. 7495-7498. Date of Electronic Publication: 2024 Jul 16. - Publication Year :
- 2024
-
Abstract
- Oxidative cyclization of 4-penten-1-ols using a Pd catalyst and n -BuONO or n -BuONO/ p -benzoquinone afforded 3-hydroxy- and 3-methoxytetrahydropyrans via terminal selective nucleophilic attack. The radicals formed from n -BuONO and O <subscript>2</subscript> operate as critical oxidants and ligands for Pd.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 60
- Issue :
- 58
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 38946406
- Full Text :
- https://doi.org/10.1039/d4cc02451f