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Anodic Electrodeposition of IrO x Nanoparticles from Aqueous Nanodroplets.
- Source :
-
ACS nanoscience Au [ACS Nanosci Au] 2024 Apr 18; Vol. 4 (3), pp. 216-222. Date of Electronic Publication: 2024 Apr 18 (Print Publication: 2024). - Publication Year :
- 2024
-
Abstract
- Electrodeposition has been used for centuries to create new materials. However, synthetic platforms are still necessary to enrich a variety of nanomaterials that can be electrodeposited. For instance, IrO <subscript> x </subscript> is a popular material for the water oxidation reaction, but electrodeposition strategies for the controlled growth of IrO <subscript> x </subscript> nanoparticles are lacking. Here, we demonstrate the anodic electrodeposition of IrO <subscript> x </subscript> nanoparticles from aqueous nanodroplets. Field emission scanning electron microscopy (FESEM) and scanning transmission electron microscopy (STEM) images confirm the macro- and microstructure of the resulting nanoparticles. IrO <subscript> x </subscript> nanoparticles of 43 ± 10 nm in diameter were achieved. X-ray photoelectron spectroscopy (XPS) showed the presence of Ir(III) and Ir(IV) hydrated oxyhydroxide species. The synthesis of IrO <subscript> x </subscript> nanoparticles under anodic conditions using water nanodroplets expands the capabilities of our technique and provides a tunable platform for IrO <subscript> x </subscript> nanoparticle electrodeposition.<br />Competing Interests: The authors declare no competing financial interest.<br /> (© 2024 The Authors. Published by American Chemical Society.)
Details
- Language :
- English
- ISSN :
- 2694-2496
- Volume :
- 4
- Issue :
- 3
- Database :
- MEDLINE
- Journal :
- ACS nanoscience Au
- Publication Type :
- Academic Journal
- Accession number :
- 38912286
- Full Text :
- https://doi.org/10.1021/acsnanoscienceau.3c00061