The Structure Characteristics of Laminar Premixed Flames of Gasoline-like Fuel Under CI Engine-Relevant Conditions.

Gasoline compression ignition characterized by partially premixed and long ignition delays typically features complex flame structures such as deflagration or spontaneous ignition fronts. In this study, the flame structure and propagation characteristics of PRF90/air mixtures under compression ignition engine-relevant conditions are investigated numerically. Similar to other types of fuels, under such conditions, the propagation speed of PRF90 laminar premixed flames depends not only on the unburnt mixture properties but also on the residence time, and the transition of the flame regime depends only on the residence time. Nevertheless, due to the temperature-dependent autoignition chemistry of PRF90, flames with excessively high unburnt temperatures show different combustion behaviors after the transition from deflagration to autoignition-assisted flames. Sensitivity analysis showed that, the dominant chain branching reactions in the deflagration mode are H + O ₂ = OH + O and CO + OH = CO ₂ + H, and that in the autoignition-assisted flames with lower unburnt temperature are H ₂ O ₂ (+M) = 2OH(+M) and IC ₈ H ₁₈ + HO ₂ = AC ₈ H ₁₇ + H ₂ O ₂ , while for higher unburnt temperatures, the reactions C ₃ H ₅ + HO ₂ = C ₂ H ₃ + CH ₂ O + OH and IC ₈ H ₁₈ = IC ₄ H ₉ + TC ₄ H ₉ are more important than the fuel low-temperature oxidation reactions. In addition, a criterion based on chemical explosive mode analysis is used to analyze the local combustion mode. The results show that the difference in diffusion/chemical structure at the crossover progress variables C ₀ and crossover temperature allows both C ₀ and to be used as a flame location for distinguishing propagation modes in premixed flame. However, the effects of the equivalence ratio on C ₀ are different from that on , which means that the selection of C ₀ and may lead to different discriminant results for stratified mixtures. Comparing the applicability of C ₀ -based and -based locations in three-dimensional gasoline compression ignition flame, it is found that the flame location based on the value of C ₀ at ϕ = 1.0 can more completely reflect the flame development characteristics in stratified premixed combustion.
Competing Interests: The authors declare no competing financial interest.
(© 2024 The Authors. Published by American Chemical Society.)