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Gold-Catalyzed Reactions of Enynals with Alkenes for Synthesis Binaphthyl Derivatives.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2024 May 03; Vol. 89 (9), pp. 6074-6084. Date of Electronic Publication: 2024 Apr 16. - Publication Year :
- 2024
-
Abstract
- A PPh <subscript>3</subscript> Au[B(C <subscript>6</subscript> F <subscript>5</subscript> ) <subscript>4</subscript> ]-catalyzed reaction of enynals and alkenes for the construction of binaphthyl derivatives was described. This transformation was achieved through o -Quinodimethane ( o -QDM) intermediate's extended conjugated addition process. The reaction has the advantages of wide substrate scopes, mild reaction conditions, high efficiency, and good scalability.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 89
- Issue :
- 9
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 38626391
- Full Text :
- https://doi.org/10.1021/acs.joc.4c00036