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Decarboxylative C-N Coupling of 2,2-Difluorobicyclo[1.1.1]pentane (BCP-F 2 ) Building Blocks.
- Source :
-
Organic letters [Org Lett] 2024 Mar 08; Vol. 26 (9), pp. 1947-1951. Date of Electronic Publication: 2024 Feb 22. - Publication Year :
- 2024
-
Abstract
- Described herein is our effort toward achieving the decarboxylative functionalization of 2,2-difluorobicyclo[1.1.1]pentane (BCP-F <subscript>2</subscript> ) building blocks. When compared with the nonfluorinated bicyclo[1.1.1]pentane (BCP) analogues, we discovered divergent reactivities. This is the first successful decarboxylative coupling of BCP-F <subscript>2</subscript> building blocks reported via the photoredox mechanism.
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 26
- Issue :
- 9
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 38386927
- Full Text :
- https://doi.org/10.1021/acs.orglett.4c00307