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Dial-a-base mechanochemical synthesis of N-heterocyclic carbene copper complexes.

Authors :
Babula DJ
Charman RSC
Hobson JA
Mahon MF
Liptrot DJ
Source :
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2024 Feb 27; Vol. 53 (9), pp. 3990-3993. Date of Electronic Publication: 2024 Feb 27.
Publication Year :
2024

Abstract

Liquid assisted ball milling of [NHC]HBr (NHC = N-heterocyclic carbene) salts with copper(I) chloride, and a range of alkali metal complexes was shown to efficiently produce (NHC)CuX (NHC = normal or RE-NHC, X = halide, alkoxide, amide, alkyl, aryl; RE-NHC = ring-expanded NHC).

Details

Language :
English
ISSN :
1477-9234
Volume :
53
Issue :
9
Database :
MEDLINE
Journal :
Dalton transactions (Cambridge, England : 2003)
Publication Type :
Academic Journal
Accession number :
38372037
Full Text :
https://doi.org/10.1039/d4dt00334a