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Enhanced efficiency of photocatalytically synthesised Co 3+ /Co 2+ -incorporated CeO 2 /SnO 2 nanocomposite and supercapacitor studies.

Authors :
Silambarasan R
Sai Sundar Perisetti US
Pavalamalar S
Anbalagan K
Source :
RSC advances [RSC Adv] 2024 Jan 30; Vol. 14 (6), pp. 4153-4164. Date of Electronic Publication: 2024 Jan 30 (Print Publication: 2024).
Publication Year :
2024

Abstract

The photochemical reduction approach, distilled H <subscript>2</subscript> O with Pr <superscript>i</superscript> OH as the solvent medium, was used to create and characterise the conversion of Co <superscript>3+</superscript> to Co <superscript>2+</superscript> integrated on CeO <subscript>2</subscript> /SnO <subscript>2</subscript> . The PXRD, IR, SEM, HR-TEM, VSM, and XPS results show that the materials generated have appropriate crystallisation form and retain the hollow spherical structure of Co-CeO <subscript>2</subscript> /SnO <subscript>2</subscript> . The performance of several UV-light energetic photocatalysts and the reaction pathways for inorganic complex degradation are addressed, emphasising the main elements contributing to their mineralisation. Reaction mechanisms, identification and quantification of degradation intermediates, and effects of reactive active species were described and analysed for each modelled target inorganic pollutant category. The ternary (Co <superscript>3+</superscript> /Co <superscript>2+</superscript> )/CeO <subscript>2</subscript> /SnO <subscript>2</subscript> materials were hypothesised to improve the photocatalytic activity by increasing the transport rate of e <subscript>CB</subscript> <superscript>-</superscript> impurities as a result of accelerating the practical separation of electron-hole (e <superscript>-</superscript> /h <superscript>+</superscript> ) pairs. Then, it exhibits high cycling stability by successfully reducing the pulverisation of Co-CeO <subscript>2</subscript> /SnO <subscript>2</subscript> electrode materials due to volume expansion and a high specific capacity of 827 F g <superscript>-1</superscript> (1 A g <superscript>-1</superscript> ) while maintaining a high current density of 5 A g <superscript>-1</superscript> . GCD and impedance spectroscopy studies were also carried out to analyse charge-discharge cycles and sample stability. This exceptional electrochemical performance suggests that Co-CeO <subscript>2</subscript> /SnO <subscript>2</subscript> are promising for high-performance energy storage systems.<br />Competing Interests: There are no conflicts of interest to declare.<br /> (This journal is © The Royal Society of Chemistry.)

Details

Language :
English
ISSN :
2046-2069
Volume :
14
Issue :
6
Database :
MEDLINE
Journal :
RSC advances
Publication Type :
Academic Journal
Accession number :
38292258
Full Text :
https://doi.org/10.1039/d3ra07947c