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A flexible semiconductor SERS substrate by in situ growth of tightly aligned TiO 2 for in situ detection of antibiotic residues.
- Source :
-
Mikrochimica acta [Mikrochim Acta] 2024 Jan 29; Vol. 191 (2), pp. 113. Date of Electronic Publication: 2024 Jan 29. - Publication Year :
- 2024
-
Abstract
- Semiconductor materials have become a competitive candidate for surface-enhanced Raman scattering (SERS) substrate. However, powdered semiconductors are difficult to execute a fast in situ detection for trace analytes. Here, we developed a new flexible semiconductor SERS substrate by in situ densely growing anatase TiO <subscript>2</subscript> nanoparticles on the surface of cotton fabric through a filtration-hydrothermal method, in which TiO <subscript>2</subscript> exhibits excellent controllability in size and distribution by regulating the ratio of water to alcohol in synthesis and the number of filtration-hydrothermal repetitive cycle. Cotton fabric/TiO <subscript>2</subscript> (Cot/TiO <subscript>2</subscript> ) substrate exhibits a high SERS activity and excellent spectral repeatability. The developed substrate has an ultra-high stability that can withstand long-term preservation; it can even resist the corrosions of strong acid and alkali, as well as high temperature up to 100 °C and low temperature down to - 20 °C. The flexible substrate can be used to carry out a rapid in situ detection for quinolone antibiotic (enrofloxacin and enoxacin) residues on the fish body surface by using a simple swabbing method, with high quantitative detection potential (up to an order of magnitude of 10 <superscript>-7</superscript>  M), and even for the simultaneous detection of both drug residues. The flexible substrate also exhibits an excellent recyclability up to 6 recycles in the actual SERS detection.<br /> (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature.)
Details
- Language :
- English
- ISSN :
- 1436-5073
- Volume :
- 191
- Issue :
- 2
- Database :
- MEDLINE
- Journal :
- Mikrochimica acta
- Publication Type :
- Academic Journal
- Accession number :
- 38286863
- Full Text :
- https://doi.org/10.1007/s00604-024-06193-8