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Efficient solid- and solution-state emissive reusable solvatochromic fluorophores for colorimetric and fluorometric detection of CN .

Efficient solid- and solution-state emissive reusable solvatochromic fluorophores for colorimetric and fluorometric detection of CN .

Authors :
Maji A
Aich K
Biswas A
Gharami S
Bera B
Mondal TK
Source :
The Analyst [Analyst] 2024 Feb 26; Vol. 149 (5), pp. 1557-1570. Date of Electronic Publication: 2024 Feb 26.
Publication Year :
2024

Abstract

In this work, a novel organic receptor, CPI [( E )-3-(4-(9 H -carbazol-9-yl)phenyl)-2-(1 H -benzo[ d ]imidazol-2-yl)acrylonitrile], was rationally designed and successfully fabricated for selective and sole recognition of CN <superscript>-</superscript> ions over other competitive anions through an obvious chromogenic and ratiometric emission change in DMSO. The distinct and prominent color change upon the addition of CN <superscript>-</superscript> can be attributed to the typical ICT process, which is induced by the deprotonation of acidic NH protons in the imidazole moiety. The sensor displayed strong solvatochromic effects in commonly used organic solvents such as n -hexane, toluene, diethyl ether, DCM, THF, DMF and DMSO. The chemical structure of the sensor was characterized by single-crystal X-ray diffraction, <superscript>1</superscript> HNMR, <superscript>13</superscript> CNMR, IR and mass spectroscopy. Significantly, the probe can function as a fluorescence-based sensor for the efficient detection of low-level water in organic solvents. The solid-state emission properties of CPI were successfully applied to recognise cyanide in a solid-state platform with naked eye-visualized distinct color change. The probe can be made reusable by adding TFA into the CN <superscript>-</superscript> treated probe solution. The detection limit of CPI towards CN <superscript>-</superscript> was determined to be 4.48 × 10 <superscript>-8</superscript> M. More importantly, the sensor is capable of detecting CN <superscript>-</superscript> in food samples and has been employed for wastewater treatment. Besides, easy-to-prepare CPI-coated test strips provide a simple, reusable and easy-to-handle protocol for the qualitative identification of CN <superscript>-</superscript> conveniently. Finally, density functional theory and time-dependent density functional theory were performed to verify the experimental outcomes theoretically.

Details

Language :
English
ISSN :
1364-5528
Volume :
149
Issue :
5
Database :
MEDLINE
Journal :
The Analyst
Publication Type :
Academic Journal
Accession number :
38284868
Full Text :
https://doi.org/10.1039/d3an01697h