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Nitrous oxide activation by picoline-derived Ni-CNP hydrides.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Feb 06; Vol. 60 (12), pp. 1575-1578. Date of Electronic Publication: 2024 Feb 06. - Publication Year :
- 2024
-
Abstract
- Oxygen atom transfer (OAT) from N <subscript>2</subscript> O to the Ni-H bond of proton-responsive picoline-derived CNP nickel complexes has been investigated both experimentally and theoretically. These Ni-CNP complexes efficiently catalyse the reduction of N <subscript>2</subscript> O with pinacolborane (HBpin) under mild conditions.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 60
- Issue :
- 12
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 38230654
- Full Text :
- https://doi.org/10.1039/d3cc05455a