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Selective dehydrogenation of ammonia borane to polycondensated BN rings catalysed by ruthenium olefin complexes.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jan 18; Vol. 60 (7), pp. 885-888. Date of Electronic Publication: 2024 Jan 18. - Publication Year :
- 2024
-
Abstract
- Dehydrogenation of ammonia borane to well-defined products is an important but challenging reaction. A dinuclear ruthenium complex with a Ru-Ru bond bearing a diazadiene (dad) unit and olefins as non-innocent ligands catalyzes the highly selective formation of conjugated polycondensed borazine oligomers (B <subscript> x </subscript> N <subscript> x </subscript> H <subscript> y </subscript> ), predominantly B <subscript>21</subscript> N <subscript>21</subscript> H <subscript>18</subscript> , the BN analogue of superbenzene.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 60
- Issue :
- 7
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 38165285
- Full Text :
- https://doi.org/10.1039/d3cc05709g