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Palladium-Catalyzed Regioselective Synthesis of 2-SF 5 -Indenols and Further Derivatizations.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Feb 12; Vol. 63 (7), pp. e202315909. Date of Electronic Publication: 2024 Jan 11. - Publication Year :
- 2024
-
Abstract
- A palladium-catalyzed synthesis of 2-SF <subscript>5</subscript> -indenols has been developed by reacting commercially available boronic acid derivatives and readily accessible SF <subscript>5</subscript> -alkynes. The present methodology is fully regioselective thanks to the intrinsic polarization of SF <subscript>5</subscript> -alkynes. A selection of downstream functionalizations has been performed to highlight the versatility of 2-SF <subscript>5</subscript> -indenols and indenones as platforms for the design of more complex SF <subscript>5</subscript> -containing molecules.<br /> (© 2023 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 63
- Issue :
- 7
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 38116823
- Full Text :
- https://doi.org/10.1002/anie.202315909