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Photocatalytic Radical Coupling of Organoborates with α-Halogenated Electron-Poor Olefins.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2024 Jan 05; Vol. 89 (1), pp. 633-643. Date of Electronic Publication: 2023 Dec 11. - Publication Year :
- 2024
-
Abstract
- Herein, we report the visible-light-mediated addition of organoborates to α-halogenated electron-poor olefins enabled by an environmentally benign metal-free catalyst. The method accommodates a variety of boronic acid derivatives as well as alkenes and delivers the corresponding saturated α-halo-derivatives in up to 90% yields. The obtained products are high-value building blocks in organic synthesis, allowing for a variety of follow-up transformations.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 89
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 38079578
- Full Text :
- https://doi.org/10.1021/acs.joc.3c02386