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Amine-modified polyionic liquid supports enhance the efficacy of PdNPs for the catalytic hydrogenation of CO 2 to formate.

Authors :
Paterson R
Fahy LE
Arca E
Dixon C
Wills CY
Yan H
Griffiths A
Collins SM
Wu K
Bourne RA
Chamberlain TW
Knight JG
Doherty S
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 Nov 09; Vol. 59 (90), pp. 13470-13473. Date of Electronic Publication: 2023 Nov 09.
Publication Year :
2023

Abstract

Palladium nanoparticles stabilised by aniline modified polymer immobilised ionic liquid is a remarkably active catalyst for the hydrogenation of CO <subscript>2</subscript> to formate; the initial TOF of 500 h <superscript>-1</superscript> is markedly higher than either unmodified catalyst or its benzylamine and N , N -dimethylaniline modified counterparts and is among the highest to be reported for a PdNP-based catalyst.

Details

Language :
English
ISSN :
1364-548X
Volume :
59
Issue :
90
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
37877311
Full Text :
https://doi.org/10.1039/d3cc04987f