Back to Search
Start Over
Unusual cleavage of phosphaalkynes triple bond in the coordination sphere of transition metals.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2023 Nov 07; Vol. 52 (43), pp. 15656-15659. Date of Electronic Publication: 2023 Nov 07. - Publication Year :
- 2023
-
Abstract
- The reaction of RCP (R = Me, t Bu, iPr) with Co <subscript>2</subscript> (CO) <subscript>8</subscript> and Fe <subscript>2</subscript> (CO) <subscript>9</subscript> under mild conditions led to unpredictable fragmentations of the CP triple bond and subsequent formation of clusters with a dimeric Co <subscript>3</subscript> E (E = P and RC) and an Fe <subscript>3</subscript> P(CR) core, respectively.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 52
- Issue :
- 43
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 37846749
- Full Text :
- https://doi.org/10.1039/d3dt02472e