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NHC-mediated photocatalytic deoxygenation of alcohols for the synthesis of internal alkynes via a Csp 3 -Csp coupling reaction.
- Source :
-
Organic & biomolecular chemistry [Org Biomol Chem] 2023 Aug 23; Vol. 21 (33), pp. 6693-6696. Date of Electronic Publication: 2023 Aug 23. - Publication Year :
- 2023
-
Abstract
- NHC-mediated deoxygenation of alcohols under photocatalytic conditions is described. The process provides various alkyl radicals, which can react with 1-bromoalkyne via Csp <superscript>3</superscript> -Csp coupling to afford internal alkynes in moderate to good yields. The method offers a new and convenient approach to synthesize internal alkynes.
Details
- Language :
- English
- ISSN :
- 1477-0539
- Volume :
- 21
- Issue :
- 33
- Database :
- MEDLINE
- Journal :
- Organic & biomolecular chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 37548245
- Full Text :
- https://doi.org/10.1039/d3ob01066j