Effects of wavelength on the treatment of contaminants of emerging concern by UV-assisted homogeneous advanced oxidation/reduction processes.

Pollutants of emerging concern in aqueous environments present a significant threat to both the aquatic ecosystem and human health due to their rapid transfer. Among the various treatment approaches to remove those pollutants, UV-assisted advanced oxidation/reduction processes are considered competent and cost-effective. The treatment effectiveness is highly dependent on the wavelength of the UV irradiation used. This article systematically discusses the wavelength dependency of direct photolysis, UV/peroxides, UV/chlor(am)ine, UV/ClO ₂ , UV/natural organic matter, UV/nitrate, and UV/sulfite on the transformation of contaminants. Altering wavelengths affects the photolysis of target pollutants, photo-decay of the oxidant/reductant, and quantum yields of reactive species generated in the processes, which significantly impact the degradation rates and formation of disinfection byproducts. In general, the degradation of contaminants is most efficient when using wavelengths that closely match the highest molar absorption coefficients of the target pollutants or the oxidizing/reducing agents, and the contribution of pollutant absorption is generally more significant. By matching the wavelength with the peak absorbance of target compounds and oxidants/reductants, researchers and engineers have the potential to optimize the UV wavelengths used in UV-AO/RPs to effectively remove pollutants and control the formation of disinfection byproducts.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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