Photoacoustic spectroscopy-based ppb-level multi-gas sensor using symmetric multi-resonant cavity photoacoustic cell.

In this paper, we propose and experimentally demonstrate a symmetric multi-resonant cavity photoacoustic cell (MR-PAC) with dual microphones detection, based on multi-resonator photoacoustic spectroscopy (MR-PAS). The designed photoacoustic cell contains three interconnected acoustic resonators to facilitate simultaneous control of three lasers for multi-gas sensing. Two microphones are symmetrically located at both sides of photoacoustic cell to implement two-point detection. The length of acoustic resonator is about 50 mm to minimize the photoacoustic cell, and the resonant frequency is around 3000 Hz. Feasibility and performance of the MR-PAC was demonstrated by simultaneous detection of C ₂ H ₂ , NO and CF ₄ using a near infrared diode laser and two mid infrared quantum cascade lasers. The minimum detection limits (MDLs) of C ₂ H ₂ , NO and CF ₄ are 480 ppb, 260 ppb and 0.57 ppb respectively with a 1 s integration time at normal atmospheric pressure. This minimized MR-PAS system is promising for the portable multi-gas sensing.
Competing Interests: The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: CHAOTAN SIMA reports financial support was provided by National Natural Science Foundation of China. PING LU reports financial support was provided by National Natural Science Foundation of China. PING LU reports financial support was provided by Science Fund for Creative Research Groups of the Nature Science Foundation of Hubei.
(© 2023 The Authors.)