Chemical and Physical Properties of YHg 3 and LuHg 3 .

Authors :: Witthaut K
Prots Y
Zaremba N
Krnel M
Leithe-Jasper A
Grin Y
Svanidze E
Source :: ACS organic & inorganic Au [ACS Org Inorg Au] 2023 Feb 02; Vol. 3 (3), pp. 143-150. Date of Electronic Publication: 2023 Feb 02 (Print Publication: 2023).
Publication Year :: 2023
Abstract: Amalgams have played an important role in fundamental and applied solid-state chemistry and physics because of the diversity of crystallographic features and properties that they have to offer. Moreover, their peculiar chemical properties can sometimes give rise to unconventional superconducting or magnetic ground states. In the current work, we present an in-depth analysis of single crystals of YHg <subscript>3</subscript> and LuHg <subscript>3</subscript> (Mg <subscript>3</subscript> Cd structure type, space group P 6 <subscript>3</subscript> / mmc ). Both compounds show superconductivity below T <subscript>c</subscript> = 1 ± 0.1 K (YHg <subscript>3</subscript> ) and T <subscript>c</subscript> = 1.2 ± 0.1 K (LuHg <subscript>3</subscript> ). Given the high air-sensitivity and toxicity of these compounds, this study was only possible using a number of dedicated experimental techniques.<br />Competing Interests: The authors declare no competing financial interest.<br /> (© 2023 The Authors. Published by American Chemical Society.)