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Visible-light-driven oxidation of organosilanes by a charge-transfer complex.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 May 25; Vol. 59 (43), pp. 6588-6591. Date of Electronic Publication: 2023 May 25. - Publication Year :
- 2023
-
Abstract
- Direct oxidation of organosilanes is one of the most straightforward ways to access silanols. Herein, we describe a novel photo-induced strategy for oxidation of organosilanes to access silanols, promoted by a photoactive charge-transfer complex (CTC) between sodium benzenesulfinate and molecular O <subscript>2</subscript> . A streamlined sequence transformation of organosilanes to silyl ethers was also readily achieved. This developed protocol represents the first example of CTC-based oxidation of organosilanes, offering a facile approach to access a series of silanol and silyl ether products.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 59
- Issue :
- 43
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 37190787
- Full Text :
- https://doi.org/10.1039/d3cc01972a