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A new satellite of manganese revealed by extended-range high-energy-resolution fluorescence detection.

Authors :
Tran NTT
Sier D
Kirk T
Tran CQ
Mosselmans JFW
Diaz-Moreno S
Chantler CT
Source :
Journal of synchrotron radiation [J Synchrotron Radiat] 2023 May 01; Vol. 30 (Pt 3), pp. 605-612. Date of Electronic Publication: 2023 Apr 07.
Publication Year :
2023

Abstract

The discovery of a new physical process in manganese metal is reported. This process will also be present for all manganese-containing materials in condensed matter. The process was discovered by applying our new technique of XR-HERFD (extended-range high-energy-resolution fluorescence detection), which was developed from the popular high-resolution RIXS (resonant inelastic X-ray scattering) and HERFD approaches. The acquired data are accurate to many hundreds of standard deviations beyond what is regarded as the criterion for `discovery'. Identification and characterization of many-body processes can shed light on the X-ray absorption fine-structure spectra and inform the scientist on how to interpret them, hence leading to the ability to measure the dynamical nanostructures which are observable using the XR-HERFD method. Although the many-body reduction factor has been used universally in X-ray absorption spectroscopy in analysis over the past 30 years (thousands of papers per year), this experimental result proves that many-body effects are not representable by any constant reduction factor parameter. This paradigm change will provide the foundation for many future studies and X-ray spectroscopy.<br /> (open access.)

Details

Language :
English
ISSN :
1600-5775
Volume :
30
Issue :
Pt 3
Database :
MEDLINE
Journal :
Journal of synchrotron radiation
Publication Type :
Academic Journal
Accession number :
37026392
Full Text :
https://doi.org/10.1107/S1600577523002539