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Selective Catalytic Behavior Induced by Crystal-Phase Transformation in Well-Defined Bimetallic Pt-Sn Nanocrystals.
- Source :
-
Small (Weinheim an der Bergstrasse, Germany) [Small] 2023 May; Vol. 19 (20), pp. e2207956. Date of Electronic Publication: 2023 Feb 20. - Publication Year :
- 2023
-
Abstract
- The Pt-Sn bimetallic system is a much studied and commercially used catalyst for propane dehydrogenation. The traditionally prepared catalyst, however, suffers from inhomogeneity and phase separation of the active Pt-Sn phase. Colloidal chemistry offers a route for the synthesis of Pt-Sn bimetallic nanoparticles (NPs) in a systematic, well-defined, tailored fashion over conventional methods. Here, the successful synthesis of well-defined ≈2 nm Pt, PtSn, and Pt <subscript>3</subscript> Sn nanocrystals with distinct crystallographic phases is reported; hexagonal close packing (hcp) PtSn and fcc Pt <subscript>3</subscript> Sn show different activity and stability depending on the hydrogen-rich or poor environment in the feed. Moreover, face centred cubic (fcc) Pt <subscript>3</subscript> Sn/Al <subscript>2</subscript> O <subscript>3</subscript> , which exhibited the highest stability compared to hcp PtSn, shows a unique phase transformation from an fcc phase to an L1 <subscript>2</subscript> -ordered superlattice. Contrary to PtSn, H <subscript>2</subscript> cofeeding has no effect on the Pt <subscript>3</subscript> Sn deactivation rate. The results reveal structural dependency of the probe reaction, propane dehydrogenation, and provide a fundamental understanding of the structure-performance relationship on emerging bimetallic systems.<br /> (© 2023 Wiley-VCH GmbH.)
Details
- Language :
- English
- ISSN :
- 1613-6829
- Volume :
- 19
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- Small (Weinheim an der Bergstrasse, Germany)
- Publication Type :
- Academic Journal
- Accession number :
- 36807838
- Full Text :
- https://doi.org/10.1002/smll.202207956