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Rh(III)-catalyzed synthesis of amino-side-chained poly(phenylene vinylene) via C-H bond olefination.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 Mar 07; Vol. 59 (20), pp. 2946-2949. Date of Electronic Publication: 2023 Mar 07. - Publication Year :
- 2023
-
Abstract
- A Rh(III)-catalyzed hydrazine-directed C-H olefination approach was developed for synthesizing amino-side-chained poly(phenylene vinylene) (PPV). The creation of such a divergent portfolio of PPV candidates enabled the discovery of a mega Stokes shift, high fluorescence quantum yield, and solid-state fluorescence, highlighting the great prospects of our synthetic protocol as an innovative tool.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 59
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 36799453
- Full Text :
- https://doi.org/10.1039/d3cc00087g