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OLYMPIA-LILBID: A New Laboratory Setup to Calibrate Spaceborne Hypervelocity Ice Grain Detectors Using High-Resolution Mass Spectrometry.

Authors :
Sanderink A
Klenner F
Zymak I
Žabka J
Postberg F
Lebreton JP
Gaubicher B
Charvat A
Abel B
Polášek M
Cherville B
Thirkell L
Briois C
Source :
Analytical chemistry [Anal Chem] 2023 Feb 21; Vol. 95 (7), pp. 3621-3628. Date of Electronic Publication: 2023 Feb 08.
Publication Year :
2023

Abstract

The coupling of an Orbitrap-based mass analyzer to the laser-induced liquid beam ion desorption (LILBID) technique has been investigated, with the aim to reproduce the mass spectra recorded by Cassini's Cosmic Dust Analyzer (CDA) in the vicinity of Saturn's icy moon Enceladus. LILBID setups are usually coupled with time-of-flight (TOF) mass analyzers, with a limited mass resolution (∼800 m /Δ m ). Thanks to the Orbitrap technology, we developed a unique analytical setup that is able to simulate hypervelocity ice grains' impact in the laboratory (at speeds in the range of 15-18 km/s) with an unprecedented high mass resolution of up to 150 000 m /Δ m (at m/z 19 for a 500 ms signal duration). The results will be implemented in the LILBID database and will be useful for the calibration and future data interpretation of the Europa Clipper's SUrface Dust Analyzer (SUDA), which will characterize the habitability of Jupiter's icy moon Europa.

Details

Language :
English
ISSN :
1520-6882
Volume :
95
Issue :
7
Database :
MEDLINE
Journal :
Analytical chemistry
Publication Type :
Academic Journal
Accession number :
36753610
Full Text :
https://doi.org/10.1021/acs.analchem.2c04429