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Cs(Pb,Mn)Br 3 Quantum Dots Glasses with Superior Thermal Stability for Contactless Electroluminescence Green-Emitting LEDs.
- Source :
-
Nanomaterials (Basel, Switzerland) [Nanomaterials (Basel)] 2022 Dec 20; Vol. 13 (1). Date of Electronic Publication: 2022 Dec 20. - Publication Year :
- 2022
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Abstract
- CsPbX <subscript>3</subscript> (X = Cl, Br or I) perovskite quantum dots (PQDs) have gained increasing interest due to their superior performance in photoelectric applications. In our work, a series of Mn <superscript>2+</superscript> doped CsPbBr <subscript>3</subscript> PQDs were successfully prepared in glasses by melt quenching and in situ crystallization technique. Due to the <superscript>4</superscript> T <subscript>1</subscript> ( <superscript>4</superscript> G)→ <superscript>6</superscript> A <subscript>1</subscript> ( <superscript>6</superscript> S) transition of Mn <superscript>2+</superscript> , a slight red shift from 510 nm to 516 nm was found, with the FWHM expansion from 18 nm to 26 nm. The PQDs@glasses showed excellent thermal stability, and the exciton binding energy reached a high level of 412 meV. The changes of the electronic structure after Mn doping CsPbBr <subscript>3</subscript> can be demonstrated by first principles. Finally, a contactless electroluminescence device with the PQDs@glasses was designed based on the principle of electromagnetic induction, which is a potential application for detecting distance in sterile and dust-free environments.
Details
- Language :
- English
- ISSN :
- 2079-4991
- Volume :
- 13
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- Nanomaterials (Basel, Switzerland)
- Publication Type :
- Academic Journal
- Accession number :
- 36615927
- Full Text :
- https://doi.org/10.3390/nano13010017